V(1.42)in(1.83)mo(15)se(19).
Identifieur interne : 001664 ( Main/Exploration ); précédent : 001663; suivant : 001665V(1.42)in(1.83)mo(15)se(19).
Auteurs : RBID : pubmed:21587348Abstract
The structure of the title compound, vanadium indium penta-deca-molybdenum nona-deca-selenide, V(1.42)In(1.83)Mo(15)Se(19), is isotypic with In(2.9)Mo(15)Se(19) [Grüttner et al. (1979 ▶). Acta Cryst. B35, 285-292]. It is characterized by two cluster units Mo(6)Se(i) (8)Se(a) (6) and Mo(9)Se(i) (11)Se(a) (6) (where i represents inner and a apical atoms) that are present in a 1:1 ratio. The cluster units are centered at Wyckoff positions 2b and 2c and have point-group symmetry and , respectively. The clusters are inter-connected through additional Mo-Se bonds. In the title compound, the V(3+) cations replace the trivalent indium atoms present in In(2.9)Mo(15)Se(19), and a deficiency is observed on the monovalent indium site. One Mo, one Se and the V atom are situated on mirror planes, and two other Se atoms and the In atom are situated on threefold rotation axes.
DOI: 10.1107/S1600536810036834
PubMed: 21587348
Links toward previous steps (curation, corpus...)
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">V(1.42)in(1.83)mo(15)se(19).</title><author><name sortKey="Gougeon, Patrick" uniqKey="Gougeon P">Patrick Gougeon</name><affiliation wicri:level="3"><nlm:affiliation>Sciences Chimiques de Rennes, UMR CNRS No. 6226, Université de Rennes I - INSA Rennes, Avenue du Général Leclerc, 35042 Rennes CEDEX, France.</nlm:affiliation><country xml:lang="fr">France</country><wicri:regionArea>Sciences Chimiques de Rennes, UMR CNRS No. 6226, Université de Rennes I - INSA Rennes, Avenue du Général Leclerc, 35042 Rennes CEDEX</wicri:regionArea><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName></affiliation></author><author><name sortKey="Gall, Philippe" uniqKey="Gall P">Philippe Gall</name></author><author><name sortKey="Salloum, Diala" uniqKey="Salloum D">Diala Salloum</name></author><author><name sortKey="Potel, Michel" uniqKey="Potel M">Michel Potel</name></author></titleStmt><publicationStmt><date when="2010">2010</date><idno type="doi">10.1107/S1600536810036834</idno><idno type="RBID">pubmed:21587348</idno><idno type="pmid">21587348</idno><idno type="wicri:Area/Main/Corpus">001B45</idno><idno type="wicri:Area/Main/Curation">001B45</idno><idno type="wicri:Area/Main/Exploration">001664</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The structure of the title compound, vanadium indium penta-deca-molybdenum nona-deca-selenide, V(1.42)In(1.83)Mo(15)Se(19), is isotypic with In(2.9)Mo(15)Se(19) [Grüttner et al. (1979 ▶). Acta Cryst. B35, 285-292]. It is characterized by two cluster units Mo(6)Se(i) (8)Se(a) (6) and Mo(9)Se(i) (11)Se(a) (6) (where i represents inner and a apical atoms) that are present in a 1:1 ratio. The cluster units are centered at Wyckoff positions 2b and 2c and have point-group symmetry and , respectively. The clusters are inter-connected through additional Mo-Se bonds. In the title compound, the V(3+) cations replace the trivalent indium atoms present in In(2.9)Mo(15)Se(19), and a deficiency is observed on the monovalent indium site. One Mo, one Se and the V atom are situated on mirror planes, and two other Se atoms and the In atom are situated on threefold rotation axes.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">21587348</PMID><DateCreated><Year>2011</Year><Month>05</Month><Day>18</Day></DateCreated><DateCompleted><Year>2011</Year><Month>07</Month><Day>14</Day></DateCompleted><DateRevised><Year>2011</Year><Month>12</Month><Day>09</Day></DateRevised><Article PubModel="Electronic"><Journal><ISSN IssnType="Electronic">1600-5368</ISSN><JournalIssue CitedMedium="Internet"><Volume>66</Volume><Issue>Pt 10</Issue><PubDate><Year>2010</Year></PubDate></JournalIssue><Title>Acta crystallographica. Section E, Structure reports online</Title><ISOAbbreviation>Acta Crystallogr Sect E Struct Rep Online</ISOAbbreviation></Journal><ArticleTitle>V(1.42)in(1.83)mo(15)se(19).</ArticleTitle><Pagination><MedlinePgn>i73</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S1600536810036834</ELocationID><Abstract><AbstractText>The structure of the title compound, vanadium indium penta-deca-molybdenum nona-deca-selenide, V(1.42)In(1.83)Mo(15)Se(19), is isotypic with In(2.9)Mo(15)Se(19) [Grüttner et al. (1979 ▶). Acta Cryst. B35, 285-292]. It is characterized by two cluster units Mo(6)Se(i) (8)Se(a) (6) and Mo(9)Se(i) (11)Se(a) (6) (where i represents inner and a apical atoms) that are present in a 1:1 ratio. The cluster units are centered at Wyckoff positions 2b and 2c and have point-group symmetry and , respectively. The clusters are inter-connected through additional Mo-Se bonds. In the title compound, the V(3+) cations replace the trivalent indium atoms present in In(2.9)Mo(15)Se(19), and a deficiency is observed on the monovalent indium site. One Mo, one Se and the V atom are situated on mirror planes, and two other Se atoms and the In atom are situated on threefold rotation axes.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Gougeon</LastName><ForeName>Patrick</ForeName><Initials>P</Initials><Affiliation>Sciences Chimiques de Rennes, UMR CNRS No. 6226, Université de Rennes I - INSA Rennes, Avenue du Général Leclerc, 35042 Rennes CEDEX, France.</Affiliation></Author><Author ValidYN="Y"><LastName>Gall</LastName><ForeName>Philippe</ForeName><Initials>P</Initials></Author><Author ValidYN="Y"><LastName>Salloum</LastName><ForeName>Diala</ForeName><Initials>D</Initials></Author><Author ValidYN="Y"><LastName>Potel</LastName><ForeName>Michel</ForeName><Initials>M</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2010</Year><Month>09</Month><Day>18</Day></ArticleDate></Article><MedlineJournalInfo><Country>England</Country><MedlineTA>Acta Crystallogr Sect E Struct Rep Online</MedlineTA><NlmUniqueID>101089178</NlmUniqueID><ISSNLinking>1600-5368</ISSNLinking></MedlineJournalInfo><CommentsCorrectionsList><CommentsCorrections RefType="Cites"><RefSource>Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22</RefSource><PMID Version="1">18156677</PMID></CommentsCorrections></CommentsCorrectionsList><OtherID Source="NLM">PMC2983212</OtherID></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2010</Year><Month>9</Month><Day>06</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2010</Year><Month>9</Month><Day>14</Day></PubMedPubDate><PubMedPubDate PubStatus="epublish"><Year>2010</Year><Month>9</Month><Day>18</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2011</Year><Month>5</Month><Day>19</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2010</Year><Month>1</Month><Day>1</Day><Hour>0</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2010</Year><Month>1</Month><Day>1</Day><Hour>0</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>epublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1107/S1600536810036834</ArticleId><ArticleId IdType="pii">wm2403</ArticleId><ArticleId IdType="pubmed">21587348</ArticleId><ArticleId IdType="pmc">PMC2983212</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=IndiumV2/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001664 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001664 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= *** parameter Area/wikiCode missing ***
|area= IndiumV2
|flux= Main
|étape= Exploration
|type= RBID
|clé= pubmed:21587348
|texte= V(1.42)in(1.83)mo(15)se(19).
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:21587348" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \
| NlmPubMed2Wicri -a IndiumV2
| This area was generated with Dilib version V0.5.76. |  |